After a fire, this can cause darkness (4)
I believe the answer is:
soot
'after a fire this can cause darkness' is the definition.
Although both the answer and definition are singular nouns, I cannot see how one could define the other.
This is all the clue.
Can you help me to learn more?
(Other definitions for soot that I've seen before include "Stuff from chimneys" , "Fine carbon deposit" , "Something stuck down the chimney" , "Black chimney powder" , "Residue from burning" .)