After games start, kittens twinkle (7)
I believe the answer is:
glitter
'twinkle' is the definition.
(I've seen this before)
'after games start kittens' is the wordplay.
'after games start' becomes 'g' (I can't justify this - if you can you should give a lot more credence to this answer).
'kittens' becomes 'litter' (I've seen this before).
'g'+'litter'='GLITTER'
Can you help me to learn more?
(Other definitions for glitter that I've seen before include "Are bright" , "Decorative sparkle" , "Sparkle on cards" , "Sparkly decoration" , "Flashiness" .)