After no peace I head for caution (8)
I believe the answer is:
wariness
'for caution' is the definition.
(wariness is a kind of caution)
'after no peace i head' is the wordplay.
'after no peace' becomes 'war' (I can't justify this - if you can you should give a lot more credence to this answer).
'head' becomes 'ness' (ness is a headland).
'war'+'i'+'ness'='WARINESS'
Can you help me to learn more?
(Other definitions for wariness that I've seen before include "State of caution" , "Caution, watchfulnes" , "Circumspection" .)