Agency worker man wooed (7)
I believe the answer is:
tempted
'wooed' is the definition.
(I've seen this before)
'agency worker man' is the wordplay.
'agency worker' becomes 'temp' (temporary worker sent from an agency).
'man' becomes 'ted' (Ted is a man's name).
'temp'+'ted'='TEMPTED'
(Other definitions for tempted that I've seen before include "Decoyed" , "Drawn to" , "Seduced" , "Enticed" , "Lured as siren does" .)