Crossword Genius

Alexander's dad had a sweetheart (4)

Ross

I believe the answer is:

pope

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'alexander's' is the definition.
The answer and definition can be both people as well as being singular nouns.
Perhaps you can see an association between them that I can't see?

'dad had a sweetheart' is the wordplay.
'dad' becomes 'pop' (synonyms).
'had' means one lot of letters go next to another.
'a sweetheart' becomes 'e' (the heart/centre of 'sweet').
'pop'+'e'='POPE'

Can you help me to learn more?

(Other definitions for pope that I've seen before include "Francis < Alexander" , "Well-versed man" , "man of great authority" , "Head of Roman Catholic Church" , "Holy man" .)

I've seen this clue in the Evening Standard.
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