Amalgamate with a union (7)
I believe the answer is:
conjoin
'amalgamate with a union' is the definition.
I can't judge whether this defines the answer.
'amalgamate with a union' is the wordplay.
'amalgamate with' becomes 'con' (I can't explain this - if you can you should give a lot more credence to this answer).
'a union' becomes 'join' (synonyms).
'con'+'join'='CONJOIN'
Can you help me to learn more?
(Other definitions for conjoin that I've seen before include "put together" , "Team up with" .)