Ambitions: Stevie Nicks's song (6)
I believe the answer is:
dreams
'ambitions' is the definition.
('dream' can be a synonym of 'ambition')
I don't understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for dreams that I've seen before include "Thoughts and visions during sleep" , "Imaginings" , "'We are such stuff / As dreams are made on' (The Tempest)" , "'''We are such stuff as ... are made on'' The Tempest (6)'" , "Fantasies; fantasises" .)