An element of luminescence (6)
I believe the answer is:
radium
'an element' is the definition.
(radium is a kind of element)
I can't explain the remainder of the clue.
Can you help me to learn more?
(Other definitions for radium that I've seen before include "Curie-found element" , "Ra (atomic number 88)" , "Radioactive metal" , "Radioactive element discovered by the Curies" , "Radioactive metallic element found in pitchblende" .)