An exclusive thing to do with new bread (5)
I believe the answer is:
debar
'an exclusive thing to do' is the definition.
I can't judge whether this definition defines the answer.
'new bread' is the wordplay.
'new' indicates an anagram.
'bread' is an anagram of 'DEBAR'.
'with' is the link.
Can you help me to learn more?
(Other definitions for debar that I've seen before include "Blackball" , "Block" , "Keep out" , "Exclude - bread (anag)" , "Large advert" .)