An old flame sat in the open (7)
I believe the answer is:
exposed
'in the open' is the definition.
(I've seen this before)
'an old flame sat' is the wordplay.
'an old flame' becomes 'ex' (an ex-lover).
'sat' becomes 'posed' ('pose' can be a synonym of 'sit').
'ex'+'posed'='EXPOSED'
(Other definitions for exposed that I've seen before include "in the nude" , "Uncovered, visible" , "Without cover" , "Deprived of protection" , "Brought to light" .)