An unpopular American in a jacket (6)
I believe the answer is:
jerkin
'a jacket' is the definition.
(I know that jerkin is a type of jacket)
'an unpopular american in' is the wordplay.
'an unpopular american' becomes 'jerk' (I am not sure about this - if you are sure you should give a lot more credence to this answer).
'jerk'+'in'='JERKIN'
Can you help me to learn more?
(Other definitions for jerkin that I've seen before include "Leatherjacket" , "Tight, sleeveless, collarless jacket" , "Sleveless jacket" , "sort of jacket" , "sleeveless garment" .)