Anciently, he appeared in fine robes (4)

I believe the answer is:

nero

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'anciently he appeared' is the definition.
The definition suggests a singular noun which matches the answer.

'in fine robes' is the wordplay.
'in' indicates a hidden word.
'NERO' can be found hidden inside 'fine robes'.

Can you help me to learn more?

(Other definitions for nero that I've seen before include "Matricidal emperor" , "Tyrannical Roman emperor" , "Ancient Roman emperor" , "Roman Emperor notorious for vice and luxury" , "Roman emperor on the fiddle?" .)

I've seen this clue in the Evening Standard.

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