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Angry and tired, though not at first (3)

Ross

I believe the answer is:

hot

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'angry' is the definition.
(I've seen this in another clue)

I can't explain the remainder of the clue.

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(Other definitions for hot that I've seen before include "Very popular" , "Fiery" , "Flaming - spicy" , "Torrid" , "(Of food) spicy" .)

I've seen this clue in The Times.
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