Annoy leaving parking place (4)
I believe the answer is:
site
'place' is the definition.
(synonyms)
'annoy leaving parking' is the wordplay.
'annoy' becomes 'spite'.
'leaving' is a deletion indicator.
'parking' becomes 'p' (abbreviation on road signs).
'spite' with 'p' removed is 'SITE'.
(Other definitions for site that I've seen before include "Place for building" , "Location; locate" , "station" , "internet location" , "Where something is located" .)