Appeals to a sweetheart to be nice (6)
I believe the answer is:
please
'be nice' is the definition.
I can't tell whether this definition defines the answer.
'appeals to a sweetheart' is the wordplay.
'appeals' becomes 'pleas' (plea is a kind of appeal).
'to a sweetheart' becomes 'e' (the heart/centre of 'sweet').
'pleas'+'e'='PLEASE'
'to' acts as a link.
Can you help me to learn more?
(Other definitions for please that I've seen before include "Polite word of request" , "Cause (someone) to feel satisfied" , "Be good enough to" , "Gratify, make contented" , "Satisfy while asleep" .)