Arrogant mood, by the sound of it (4)
I believe the answer is:
vain
'arrogant' is the definition.
(thesaurus)
I cannot understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for vain that I've seen before include "Forever looking in the mirror" , "Useless; conceited" , "It's no good" , "Conceited - or a waste of time" , "Stuck-up? It's hopeless" .)