As a team, perhaps, gain promotion outright (5)
I believe the answer is:
group
'as' is the definition.
The definition and answer can be both substances as well as being singular nouns.
Perhaps they are linked in a way I don't understand?
I don't understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for group that I've seen before include "Crew" , "Aggregation" , "Set; place together" , "Number of people or items together" , "Collection" .)