As a witness, be careful! (5)
I believe the answer is:
watch
'as' is the definition.
Although both the answer and definition are singular nouns, I can't see how one could define the other.
I don't understand the remainder of the clue.
Can you help me to learn more?
(Other definitions for watch that I've seen before include "Observe - guard" , "See 21" , "period of duty" , "Observe - timepiece" , "Look at attentively" .)