As Iceland released worsening ash, you'd each head for the Channel (6)
I believe the answer is:
airway
'for the channel' is the definition.
(airway is a kind of channel)
I don't understand the rest of the clue.
Can you help me to learn more?
(Other definitions for airway that I've seen before include "Breathing passage" , "Ventilation passage" , "breathing space" , "Regular route of aircraft" , "radio channel" .)