As joined by Jack? (5)
I believe the answer is:
union
'jack?' is the definition.
(thesaurus)
I don't understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for union that I've seen before include "Workers' organisation or marriage" , "Coupling, merger" , "Equity is one" , "Marriage; trade assoc." , "The coming together of separate parts" .)