As Peel, out to give satisfaction (6)
I believe the answer is:
please
'give satisfaction' is the definition.
(I've seen this before)
'as peel out' is the wordplay.
'out' is an anagram indicator (out can mean wrong or inaccurate).
'as'+'peel'='aspeel'
'aspeel' with letters rearranged gives 'PLEASE'.
'to' is the link.
(Other definitions for please that I've seen before include "suit" , "Be good enough to" , "Polite addition to a request" , "If you'd be so kind?" , "Give satisfaction to" .)