As venomous creatures presumably they don't multiply! (6)
I believe the answer is:
adders
'as venomous' is the definition.
'adders' can be an answer for 'venomous' (type of snake). I am unsure of the 'as' bit.
I can't explain the remainder of the clue.
Can you help me to learn more?
(Other definitions for adders that I've seen before include "Dreads (anag) -- snakes" , "People doing sums" , "Snakes are totters" , "Mathematical snakes" , "Poisonous snakes" .)