As written of by Defoe once a week (6)
I believe the answer is:
friday
'week' is the definition.
The answer and definition can be both related to time as well as being singular nouns.
Perhaps they are linked in a way I don't understand?
I don't understand the rest of the clue.
Can you help me to learn more?
(Other definitions for friday that I've seen before include "Muslim Sabbath" , "Its child is loving and giving" , "It's payday for some" , "POETS day" , "Man perhaps" .)