Ask and prompt Victor to substitute Charlie (6)
I believe the answer is:
invite
'ask' is the definition.
(I know that invite is a more specific form of request)
I cannot understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for invite that I've seen before include "Ask (someone to visit)" , "Solicit" , "Ask to call" , "Encourage, ask" , "Ask round" .)