Assemble a church service (5)
I believe the answer is:
amass
'assemble' is the definition.
(I've seen this in another clue)
'a church service' is the wordplay.
'church service' becomes 'mass' (Mass is a type of church service).
'a'+'mass'='AMASS'
(Other definitions for amass that I've seen before include "store" , "Put together" , "Gather in great quantity" , "Collect, hoard" , "Gather together, pile up" .)