Associate of diplomat Spain expelled (6)
I believe the answer is:
attach
'associate' is the definition.
(I've seen this before)
I don't understand the remainder of the clue.
Can you help me to learn more?
(Other definitions for attach that I've seen before include "Append, join" , "Affix, connect" , "Add on to, couple" , "Join, connect" , "Tag on" .)