At bedtime, go to it! (5)
I believe the answer is:
sleep
'at bedtime' is the definition.
'sleep' can be an answer for 'bedtime' (thesaurus). I am unsure of the 'at' bit.
I cannot understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for sleep that I've seen before include "Wayne _; former Royal Ballet principal dancer" , "Be dormant" , "Slumber" , "''... that knits up the ravell'd sleeve of care'' (Macbeth)" , "Snooze" .)