Crossword Genius

At pleasure, a detective left one piece with hesitation (2,7)

Ross

I believe the answer is:

ad libitum

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'with hesitation' is the definition.
Both the definition and answer are adverbs. Perhaps they are linked in a way I don't understand?

'at pleasure a detective left one piece' is the wordplay.
'at pleasure' becomes 'ad lib' (I've seen this before).
'a detective left' becomes 'i' (I can't explain this - if you can you should believe this answer much more).
'one piece' becomes 'tum' (tum is a kind of piece).
'adlib'+'i'+'tum'='AD LIBITUM'

Can you help me to learn more?

(Another definition for ad libitum that I've seen is " As much and as often as desired".)

I've seen this clue in the Sydney Morning Herald.
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