Barefaced? (6)
I believe the answer is:
shaven
'barefaced?' is the definition.
Both the answer and definition are adjectives. Maybe there's a link between them I don't understand?
This is all the clue.
Can you help me to learn more?
(Other definitions for shaven that I've seen before include "lacking coverage" , "without locks" , "Without a beard" , "With hair removed (N, not D)" , "Hairless after work with razor" .)