Barista's warning police still? (7)
I believe the answer is:
mugshot
'police still?' is the definition.
(photograph or still taken by the police)
I don't understand the remainder of the clue.
(Other definitions for mugshot that I've seen before include "Police photo (colloq.)" , "Passport photograph?" , "Still capturing the culprit" , "ID photograph (colloq.)" , "Police ID photograph" .)