Be jubilant over new expensive headgear (5)
I believe the answer is:
crown
This might be a double definition.
'be' is the first definition.
(I know that crown is a more specific form of the action head)
'jubilant over new expensive headgear' is the second definition.
'crown' can be an answer for 'headgear' (crown is a kind of headgear). I am unsure of the 'jubilant over new expensive' bit.
Can you help me to learn more?
(Other definitions for crown that I've seen before include "Diadem" , "'Uneasy lies the head that wears a . . . . .'" , "Highest part; coin" , "Top of the head; coin" , "repair for damaged tooth" .)