Being caught outright, is tough (4)
I believe the answer is:
hard
'is tough' is the definition.
(synonyms)
I don't understand the rest of the clue.
Can you help me to learn more?
(Other definitions for hard that I've seen before include "Solid, firm, rigid" , "Solid; tough" , "Difficult; rigid" , "Newspaper's sure" , "Tough; rigid" .)