Being motherly makes little material difference (8)
I believe the answer is:
maternal
'being motherly' is the definition.
('maternal' can be similar in meaning to 'motherly')
I don't understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for maternal that I've seen before include "Of a mother or motherhood" , "Motherly" , "On the mother's side" , "Protective" .)