Being of a sweet and friendly disposition, I question my proficiency (7)
I believe the answer is:
amiable
'being of a sweet and friendly disposition' is the definition.
(I've seen this before)
I cannot understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for amiable that I've seen before include "'Friendly, pleasant and good-tempered (7)'" , "'Cordial, friendly (7)'" , "Friendly and good-natured (7)" , "Friendly, kindly" , "Lovable, friendly" .)