Being on edge, he starts mumbling (3)
I believe the answer is:
hem
'being on edge' is the definition.
'hem' can be an answer for 'edge' (thesaurus). I am not certain of the 'being on' bit.
'he starts mumbling' is the wordplay.
'starts' indicates taking the first letters.
The initial letter of 'mumbling' is 'm'.
'he'+'m'='HEM'
Can you help me to learn more?
(Other definitions for hem that I've seen before include "Stitched edge of garment" , "Sewn edge to fabric" , "Express hesitation" , "A stitched border of cloth" , "It draws attention to" .)