Best, despite possible lack of ultimate fitness (6)
I believe the answer is:
finest
'best' is the definition.
(I've seen this before)
I cannot understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for finest that I've seen before include "Infest with the best" , "Most splendid" , "Superior in quality" , "Most exquisite" , "Of the highest grade" .)