Best officer in uniform one with chum (8)
I believe the answer is:
ultimate
'best' is the definition.
(I've seen this before)
'officer in uniform one with chum' is the wordplay.
'officer in uniform' becomes 'ult' (I can't justify this - if you can you should give a lot more credence to this answer).
'one' becomes 'I' (Roman numeral).
'with' says to put letters next to each other.
'chum' becomes 'mate' (I've seen this before).
'ult'+'i'+'mate'='ULTIMATE'
Can you help me to learn more?
(Other definitions for ultimate that I've seen before include "The final point" , "Conclusive" , "Furthest, final" , "Eventual" , "Utmost or extreme" .)