Big sister? (6)
I believe the answer is:
abbess
'big sister?' is the definition.
(I've seen this in another clue)
This is all the clue.
(Other definitions for abbess that I've seen before include "She heads a religious community" , "Superior nun" , "one with unmarried sisters in her care" , "Head of group of nuns" , "Superior of group of nuns" .)