Bond, at heart is decent, homely and gentle (6)
I believe the answer is:
cement
'bond' is the definition.
(cement can mean to stick or bond)
I can't explain the remainder of the clue.
Can you help me to learn more?
(Other definitions for cement that I've seen before include "bind together" , "Ingredient in mortar" , "Stuff that binds or bonds" , "Ingredient of concrete" , "Stick together - substance used by a builder" .)