Book describing shyness (7)
I believe the answer is:
reserve
This clue is a double definition.
'book' is the first definition.
(as in booking or reserving in advance)
'shyness' is the second definition.
'describing' acts as a link.
(Other definitions for reserve that I've seen before include "Husband - substitute" , "put to one side" , "Set aside - shyness" , "8 [RESTRAINT]" , "Keep for future use" .)