Briefed on the first day (6)
I believe the answer is:
primed
'briefed' is the definition.
(I've seen this before)
'the first day' is the wordplay.
'the first' becomes 'prime' (I've seen this before).
'day' becomes 'd' (abbreviation for day).
'prime'+'d'='PRIMED'
'on' is the link.
(Other definitions for primed that I've seen before include "Filled in" , "charged" , "Made ready for action" , "Briefed - ready" , "Prepared something for use or action" .)