Briefly the captain I have can't get away (7)
I believe the answer is:
captive
'can't get away' is the definition.
I can't judge whether this definition defines the answer.
'briefly the captain i have' is the wordplay.
'briefly the captain' becomes 'capt' (abbreviation; 'briefly' indicates an abbreviation).
'i have' becomes 'I've' (contraction of 'I have').
'capt'+'ive'='CAPTIVE'
Can you help me to learn more?
(Other definitions for captive that I've seen before include "Prisoner" , "Detainee" .)