Burn rebellious vigilantes after irritated Slav leaves (6)
I believe the answer is:
ignite
'burn' is the definition.
(igniting is a kind of burning)
I don't understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for ignite that I've seen before include "Burn" , "Catch fire; provoke" , "Detonate" , "'Set alight, fire up (6)'" , "Cause to catch fire" .)