Burning a sack (5)
I believe the answer is:
afire
'burning' is the definition.
(thesaurus)
'a sack' is the wordplay.
'sack' becomes 'fire' ('fire' can be a synonym of 'sack').
'a'+'fire'='AFIRE'
(Other definitions for afire that I've seen before include "Burning" , "in flames" , "Blazing - excited" , "Alight" , "lit up" .)