Calculates – or guesses (7)
I believe the answer is:
reckons
This clue is a double definition.
'calculates' is the first definition.
('reckon' can be a synonym of 'calculate')
'guesses' is the second definition.
(I know this)
'or' is the link.
(Other definitions for reckons that I've seen before include "Suspects" , "Considers" , "Judges" , "Conkers (anag.)" , "Counts or guesses" .)