Can one not do so without a hitch? (5)
I believe the answer is:
marry
'hitch?' is the definition.
(thesaurus)
I don't understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for marry that I've seen before include "Well I never!" , "Tie the knot; why! (Shak.)" , "Gain a wife or husband" , "Join - get wed" , "Get hitched" .)