Cap a chap out East (5)
I believe the answer is:
beret
'cap' is the definition.
(I know that beret is a type of cap)
'a chap out east' is the wordplay.
'a chap' becomes 'Ber'.
'out east' becomes 'et' (I can't explain this - if you can you should give a lot more credence to this answer).
'ber'+'et'='BERET'
Can you help me to learn more?
(Other definitions for beret that I've seen before include "Round, brimless cap" , "French style cap" , "cover for commandos" , "French-style hat" , "Basque headgear" .)