Capital A followed by S (6)
I believe the answer is:
athens
'capital' is the definition.
(capital of Greece)
'a followed by s' is the wordplay.
'followed by' becomes 'then' (I've seen this in another clue).
'a'+'then'+'s'='ATHENS'
(Other definitions for athens that I've seen before include "EU capital" , "Greek capital" , "foreign city" , "Tan she got in Greece" , "City of the Parthenon" .)