Capital hoax, a stunning blow (6)
I believe the answer is:
bamako
'capital' is the definition.
(capital of Mali)
'hoax a stunning blow' is the wordplay.
'hoax' becomes 'bam' (I've seen this before).
'stunning blow' becomes 'ko' (KO is an example. I am not sure about the 'stunning' bit.).
'bam'+'a'+'ko'='BAMAKO'
Can you help me to learn more?
(Other definitions for bamako that I've seen before include "Capital of Mali" , "African capital" .)