Capital of Chile (8)
I believe the answer is:
santiago
<span class="explanation-format__ClueExplanation">'<span class="explanation-format__original">capital of chile</span>' is the definition.<br/ ><span class="explanation-format__explanation">(synonyms)</span><br/ ><br/ >This is the entire clue.<br/ ></span>
(Other definitions for santiago that I've seen before include "Chile's capital" , "City" , "Chilean capital" , "South American capital" , "Capital of Chile" .)